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Characteristics of the ozone decline in the Northern polar and middle latitudes during the winter-spring
Bojkov R.D., D.S. Balis and C.S. Zerefos
[περίληψη]
The total ozone decline during the past twenty years, especially strong during the winter-spring season poleward from 50o N, is well established with known average trends of 5-7% per decade.  This study presents a number of additional characteristics such as ozone-mass deficiency (O3MD) from the pre-1976 base average, and areal extent with negative deviations greater than ~2 and ~3σ.  Gridded satellite data, combined with ground-based total ozone maps, permit calculations of daily and regional ozone deficiencies from the anthropogenically undisturbed average ozone levels of the 1960s and early 1970s.  Then the quantity of the O3MD and the changes in surface area, with deficiencies larger than -10 and -15% are integrated for the 1 January to 15 April period for each of the last 20 years, and compared.  In addition, the polar vortex extent during the last 10 years is determined using the PV at 475oK.  The quantity of the O3MD within the sunlit part of the vortex is shown to contribute from ~15 to 35% of the overall ozone deficiency within the -10% contours over the area 35?90oN.  The ozone deficiency, integrated for the first 105 days of each year, has increased dramatically from ~2,800 Mt in the early 1980s to ~7,800 Mt in the 1990s, exceeded 12,000 Mt in the winter-springs of 1993 and 1995.  The latter quantity is comparable with the average O3MD over the same Southern latitudes in the last ten austral springs.  During the 1990s over the 35-50o middle latitude belts the ozone deficiency in the Southern hemisphere is less than over the Northern hemisphere by ~39%.  It is known that the main ozone decline is observed in the lower stratosphere and the ozone loss over the Arctic is very sensitive to decreasing stratospheric temperatures; negative 50hPa monthly anomalies greater than 4oC have occurred during 7 of the springs in the last decade, thus possibly facilitating doubling the area with negative ozone deviations greater than -10% in the 1990s to ~5,000Χ106  km2, and nearly tripling the O3MD as stated above. The changes in total eddy heat fluxes as a proxy indicator of the long-wave perturbations are positively correlated with the ozone deficiency in the 45-75oN.  The strong anticorrelation between the ozone deficiency in the region >55oN versus the 35-50oN belt is discussed in relation to possible transport of air masses with low ozone from the sub-tropics, which in some years are the dominant reason for the observed ozone deficiency.
[keywords]
Ozone decline, middle latitudes
Meteorology and Atmospheric Physics, 69 (1-2), pp. 119-135, 1998
 http://www.scopus.com/scopus/inward/record.url?eid=2-s2.0-0032262588&partnerID=40
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